| 27 May 2023 | Bundesliga | Borussia Dortmund - 1. FSV Mainz 05 | A | Dortmund | €4.2m | €0.07m |
| 21 May 2023 | Bundesliga | 1. FSV Mainz 05 - VfB Stuttgart | H | Mainz | €1.7m | €1.5m |
| 13 May 2023 | Bundesliga | Eintracht Frankfurt - 1. FSV Mainz 05 | A | Frankfurt am Main | €2.9m | €0.08m |
| 5 May 2023 | Bundesliga | 1. FSV Mainz 05 - Schalke 04 | H | Mainz | €1.7m | €1.5m |
| 30 Apr 2023 | Bundesliga | VfL Wolfsburg - 1. FSV Mainz 05 | A | Wolfsburg | €1.2m | €0.07m |
| 22 Apr 2023 | Bundesliga | 1. FSV Mainz 05 - FC Bayern München | H | Mainz | €1.7m | €1.5m |
| 15 Apr 2023 | Bundesliga | 1. FC Köln - 1. FSV Mainz 05 | A | Köln | €2.4m | €0.06m |
| 8 Apr 2023 | Bundesliga | 1. FSV Mainz 05 - Werder Bremen | H | Mainz | €1.7m | €1.5m |
| 1 Apr 2023 | Bundesliga | RB Leipzig - 1. FSV Mainz 05 | A | Leipzig | €2.3m | €0.07m |
| 19 Mar 2023 | Bundesliga | 1. FSV Mainz 05 - SC Freiburg | H | Mainz | €1.4m | €1.2m |
| 11 Mar 2023 | Bundesliga | Hertha BSC - 1. FSV Mainz 05 | A | Berlin | €2.5m | €0.09m |
| 4 Mar 2023 | Bundesliga | 1. FSV Mainz 05 - TSG Hoffenheim | H | Mainz | €1.5m | €1.3m |
| 24 Feb 2023 | Bundesliga | 1. FSV Mainz 05 - Borussia Mönchengladbach | H | Mainz | €1.7m | €1.5m |
| 19 Feb 2023 | Bundesliga | Bayer 04 Leverkusen - 1. FSV Mainz 05 | A | Leverkusen | €1.5m | €0.08m |
| 11 Feb 2023 | Bundesliga | 1. FSV Mainz 05 - FC Augsburg | H | Mainz | €1.1m | €0.99m |
| 4 Feb 2023 | Bundesliga | Union Berlin - 1. FSV Mainz 05 | A | Berlin | €1.3m | €0.09m |
| 1 Feb 2023 | DFB-Pokal | 1. FSV Mainz 05 - FC Bayern München | H | Mainz | €2.8m | €2.4m |
| 28 Jan 2023 | Bundesliga | 1. FSV Mainz 05 - VfL Bochum | H | Mainz | €1.2m | €1.0m |
| 25 Jan 2023 | Bundesliga | 1. FSV Mainz 05 - Borussia Dortmund | H | Mainz | €1.6m | €1.4m |
| 21 Jan 2023 | Bundesliga | VfB Stuttgart - 1. FSV Mainz 05 | A | Stuttgart | €2.4m | €0.07m |
| 13 Nov 2022 | Bundesliga | 1. FSV Mainz 05 - Eintracht Frankfurt | H | Mainz | €1.7m | €1.5m |
| 9 Nov 2022 | Bundesliga | Schalke 04 - 1. FSV Mainz 05 | A | Gelsenkirchen | €3.0m | €0.07m |
| 5 Nov 2022 | Bundesliga | 1. FSV Mainz 05 - VfL Wolfsburg | H | Mainz | €1.4m | €1.2m |
| 29 Oct 2022 | Bundesliga | FC Bayern München - 1. FSV Mainz 05 | A | München | €4.5m | €0.09m |
| 21 Oct 2022 | Bundesliga | 1. FSV Mainz 05 - 1. FC Köln | H | Mainz | €1.6m | €1.4m |
| 18 Oct 2022 | DFB-Pokal | VfB Lübeck - 1. FSV Mainz 05 | A | Lübeck | €0.85m | €0.18m |
| 15 Oct 2022 | Bundesliga | Werder Bremen - 1. FSV Mainz 05 | A | Bremen | €2.1m | €0.07m |
| 8 Oct 2022 | Bundesliga | 1. FSV Mainz 05 - RB Leipzig | H | Mainz | €1.3m | €1.2m |
| 1 Oct 2022 | Bundesliga | SC Freiburg - 1. FSV Mainz 05 | A | Freiburg im Breisgau | €1.8m | €0.07m |
| 16 Sep 2022 | Bundesliga | 1. FSV Mainz 05 - Hertha BSC | H | Mainz | €1.3m | €1.1m |
| 10 Sep 2022 | Bundesliga | TSG Hoffenheim - 1. FSV Mainz 05 | A | Sinsheim | €1.0m | €0.07m |
| 4 Sep 2022 | Bundesliga | Borussia Mönchengladbach - 1. FSV Mainz 05 | A | Mönchengladbach | €2.6m | €0.07m |
| 27 Aug 2022 | Bundesliga | 1. FSV Mainz 05 - Bayer 04 Leverkusen | H | Mainz | €1.5m | €1.3m |
| 20 Aug 2022 | Bundesliga | FC Augsburg - 1. FSV Mainz 05 | A | Augsburg | €1.2m | €0.07m |
| 14 Aug 2022 | Bundesliga | 1. FSV Mainz 05 - Union Berlin | H | Mainz | €1.3m | €1.1m |
| 6 Aug 2022 | Bundesliga | VfL Bochum - 1. FSV Mainz 05 | A | Bochum | €1.3m | €0.07m |
| 31 Jul 2022 | DFB-Pokal | Erzgebirge Aue - 1. FSV Mainz 05 | A | Aue-Bad Schlema | €0.81m | €0.07m |